Which one of the following does not exhibit the phenomenon of mutarotation?
(+)-Sucrose
(+)-Lactose
(+)-Maltose
(-)-Fructose
Mutarotation is the spontaneous change in the specific rotation of an optically active compound when dissolved in water, due to the equilibrium between its and anomeric forms. It is a characteristic property of reducing sugars. Sucrose is a non-reducing sugar because the glycosidic bond is formed between the anomeric carbon of -D-glucose (C1) and the anomeric carbon of -D-fructose (C2). Since it does not have a free anomeric hemiacetal or hemiketal hydroxyl group, it cannot undergo ring opening in solution and thus does not exhibit mutarotation.
Join thousands of students and practice with AI-generated mock tests.