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NEET CHEMISTRYEasy

Which one of the following does not exhibit the phenomenon of mutarotation?

A

(+)-Sucrose

B

(+)-Lactose

C

(+)-Maltose

D

(-)-Fructose

Step-by-Step Solution

Mutarotation is the spontaneous change in the specific rotation of an optically active compound when dissolved in water, due to the equilibrium between its α\alpha and β\beta anomeric forms. It is a characteristic property of reducing sugars. Sucrose is a non-reducing sugar because the glycosidic bond is formed between the anomeric carbon of α\alpha-D-glucose (C1) and the anomeric carbon of β\beta-D-fructose (C2). Since it does not have a free anomeric hemiacetal or hemiketal hydroxyl group, it cannot undergo ring opening in solution and thus does not exhibit mutarotation.

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