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NEET CHEMISTRYEasy

When phenol is treated with CHCl₃ and NaOH, the product formed is:

A

Benzaldehyde

B

Salicylaldehyde

C

Salicylic acid

D

Benzoic acid

Step-by-Step Solution

The reaction described is the Reimer-Tiemann reaction. When phenol is treated with chloroform (CHCl3CHCl_3) in the presence of aqueous sodium hydroxide (NaOHNaOH), an aldehyde group (CHO-CHO) is introduced at the ortho position of the benzene ring.

  1. Mechanism: The reaction proceeds via the formation of an electrophilic intermediate called dichlorocarbene (:CCl2:CCl_2).
  2. Product: The major product formed is Salicylaldehyde (2-Hydroxybenzaldehyde).

(Note: If Carbon tetrachloride, CCl4CCl_4, is used instead of Chloroform, the product is Salicylic acid).

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