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NEET CHEMISTRYMedium

Order of acidic strength of the following compounds will be: [Note: Specific structures for A, B, C, and D were not provided in the input, but typically involve Phenol and substituted phenols]

A

C > D > B > A

B

D > C > B > A

C

A > B > C > D

D

B > A > C > D

Step-by-Step Solution

The acidic strength of phenols depends on the stability of the phenoxide ion formed after the loss of a proton.

  1. Electron-Withdrawing Groups (EWG): Substituents like NO2-NO_2, CN-CN, and halogens withdraw electrons from the benzene ring via Inductive (I-I) and/or Resonance (R-R) effects. This dispersal of negative charge stabilizes the phenoxide ion, making the compound more acidic compared to phenol , . The effect is usually strongest at ortho/para positions due to resonance .
  2. Electron-Donating Groups (EDG): Substituents like alkyl groups (CH3-CH_3) or alkoxy groups release electrons (via +I+I or +R+R effects), intensifying the negative charge on the oxygen. This destabilizes the phenoxide ion, making the compound less acidic than phenol .

Note: Without the specific structures, the probable answer 'C > D > B > A' implies 'C' is likely a phenol with strong EWGs (e.g., nitrophenol) and 'A' is likely a phenol with EDGs or fewer EWGs.

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