Let the volume of each solution be V.
Moles of NaOH = 0.1×V=0.1V
Moles of HCl = 0.01×V=0.01V
The neutralization reaction is NaOH+HCl→NaCl+H2O. Since NaOH and HCl react in a 1:1 molar ratio, HCl is the limiting reagent.
Moles of NaOH left unreacted = 0.1V−0.01V=0.09V
Total volume of the resulting mixture = V+V=2V
Concentration of OH− in the final solution = 2V0.09V=0.045 M
pOH=−log[OH−]=−log(0.045)=−log(4.5×10−2)=2−log(4.5)=2−0.653=1.347
pH=14−pOH=14−1.347=12.653≈12.65.