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NEET CHEMISTRYMedium

1.00 g1.00 \text{ g} of a non-electrolyte solute (molar mass 250 g/mol250 \text{ g/mol}) was dissolved in 51.2 g51.2 \text{ g} of benzene. If the freezing point depression constant, KfK_f of benzene is 5.12 K kg mol15.12 \text{ K kg mol}^{-1}, the freezing point of benzene will be lowered by:

A

0.4 K0.4 \text{ K}

B

0.3 K0.3 \text{ K}

C

0.5 K0.5 \text{ K}

D

0.2 K0.2 \text{ K}

Step-by-Step Solution

Given: Mass of solute (w2w_2) = 1.00 g1.00 \text{ g} Molar mass of solute (M2M_2) = 250 g/mol250 \text{ g/mol} Mass of solvent (benzene, w1w_1) = 51.2 g=0.0512 kg51.2 \text{ g} = 0.0512 \text{ kg} Freezing point depression constant (KfK_f) = 5.12 K kg mol15.12 \text{ K kg mol}^{-1}

The depression in freezing point (ΔTf\Delta T_f) is given by the formula: ΔTf=Kf×m\Delta T_f = K_f \times m Where mm is the molality of the solution. m=w2M2×w1 (in kg)=1.00250×0.0512=112.8 mm = \frac{w_2}{M_2 \times w_1 \text{ (in kg)}} = \frac{1.00}{250 \times 0.0512} = \frac{1}{12.8} \text{ m}

Now, substitute the values into the equation: ΔTf=5.12×112.8=0.4 K\Delta T_f = 5.12 \times \frac{1}{12.8} = 0.4 \text{ K}

Therefore, the freezing point of benzene will be lowered by 0.4 K0.4 \text{ K}.

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