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NEET CHEMISTRYEasy

The Clemmensen reduction of a ketone is carried out in the presence of:

A

Zn-Hg with HCl

B

LiAlH4

C

H2 and Pt as a catalyst

D

Glycol with KOH

Step-by-Step Solution

Clemmensen reduction is a method to reduce the carbonyl group (>C=O>C=O) of aldehydes and ketones to a methylene group (CH2-CH_2-) to form hydrocarbons. The reagent used for this reaction is Zinc Amalgam (Zn-Hg) and concentrated Hydrochloric acid (HCl).

Comparison of other options:

  • LiAlH4: Reduces ketones to secondary alcohols.
  • H2/Pt: Catalytic hydrogenation reduces ketones to secondary alcohols.
  • Glycol with KOH: Used in Wolff-Kishner reduction (along with hydrazine) to achieve the same transformation (>C=O>C=O to CH2-CH_2-) but under basic conditions.
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