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NEET CHEMISTRYEasy

Mark the name of the reaction associated with the following conversion:

A

Stephen reaction

B

Gattermann-Koch reaction

C

Etard reaction

D

Rosenmund reaction

Step-by-Step Solution

The Rosenmund reaction is a specific hydrogenation process where an acyl chloride (acid chloride) is converted into an aldehyde. This reduction is carried out using hydrogen gas (H2H_2) in the presence of a catalyst, palladium supported on barium sulphate (Pd/BaSO4Pd/BaSO_4). The reaction scheme is generally represented as: RCOCl+H2Pd/BaSO4RCHO+HClR-COCl + H_2 \xrightarrow{Pd/BaSO_4} R-CHO + HCl

Other options refer to different preparations:

  • Stephen reaction: Reduction of nitriles to aldehydes using SnCl2/HClSnCl_2/HCl.
  • Gattermann-Koch reaction: Formylation of benzene derivatives using COCO and HClHCl with AlCl3AlCl_3.
  • Etard reaction: Oxidation of the methyl group in toluene to an aldehyde using chromyl chloride (CrO2Cl2CrO_2Cl_2).
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