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NEET CHEMISTRYEasy

Homoleptic complex from the following complexes is:

A

Triamminetriaquachromium (III)

B

Potassium trioxalatoaluminate (III)

C

Diamminechloridonitrito-N-platinum (II)

D

Pentaamminecarbonatocobalt (III) chloride

Step-by-Step Solution

Complexes in which a metal is bound to only one kind of donor groups (ligands) are known as homoleptic complexes.

  • In Potassium trioxalatoaluminate(III), K3[Al(C2O4)3]K_3[Al(C_2O_4)_3], the central metal ion Al(III) is bound to only one type of ligand, i.e., oxalato (C2O42C_2O_4^{2-}). Therefore, it is a homoleptic complex.
  • In Triamminetriaquachromium(III), the central metal is bound to two types of ligands: ammine (NH3NH_3) and aqua (H2OH_2O). So, it is heteroleptic.
  • In Diamminechloridonitrito-N-platinum(II), the central metal is bound to three types of ligands: ammine, chlorido, and nitrito-N. So, it is heteroleptic.
  • In Pentaamminecarbonatocobalt(III) chloride, the central metal is bound to two types of ligands: ammine and carbonato. So, it is heteroleptic.
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