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The freezing point depression constant (KfK_f) of benzene is 5.12 K kg mol15.12 \text{ K kg mol}^{-1}. The freezing point depression for the solution of molality 0.078 m0.078 \text{ m} containing a non-electrolyte solute in benzene is:

A

0.80 K

B

0.40 K

C

0.60 K

D

0.20 K

Step-by-Step Solution

The depression in freezing point (ΔTf\Delta T_f) is a colligative property calculated using the formula: ΔTf=i×Kf×m\Delta T_f = i \times K_f \times m

Where: KfK_f = Freezing point depression constant = 5.12 K kg mol15.12 \text{ K kg mol}^{-1} mm = Molality of the solution = 0.078 mol kg10.078 \text{ mol kg}^{-1}

  • ii = Van't Hoff factor. Since the solute is a non-electrolyte, it does not dissociate or associate, so i=1i = 1 .

Calculation: ΔTf=1×5.12×0.078\Delta T_f = 1 \times 5.12 \times 0.078 ΔTf0.39936 K\Delta T_f \approx 0.39936 \text{ K}

Rounding to two decimal places, ΔTf=0.40 K\Delta T_f = 0.40 \text{ K}.

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