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NEET CHEMISTRYMedium

What is the correct order of the carboxylic acids' strength for the compounds labeled I, II, and III?

A

I > II > III

B

II > III > I

C

III > II > I

D

II > I > III

Step-by-Step Solution

The strength of carboxylic acids depends on the stability of the carboxylate anion formed after losing a proton.

  1. Electron-Withdrawing Groups (EWG): Groups like NO2-NO_2, Cl-Cl, or CN-CN stabilize the carboxylate anion through inductive (-I) and/or resonance (-R) effects, dispersing the negative charge and increasing acidity.
  2. Electron-Donating Groups (EDG): Groups like alkyl groups (CH3-CH_3) or methoxy groups (OCH3-OCH_3) destabilize the carboxylate anion by intensifying the negative charge through inductive (+I) or resonance (+R) effects, thereby decreasing acidity.

Note: The specific structures for I, II, and III were not provided in the input. However, based on the probable answer (II > III > I), compound II likely contains the strongest electron-withdrawing group or is in a position (ortho/para) that maximizes acidity, while compound I likely contains an electron-donating group or lacks stabilizing factors.

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