According to Molecular Orbital Theory, the bond order is calculated as 21(Nb−Na), where Nb is the number of bonding electrons and Na is the number of antibonding electrons.
- O2: has 16 electrons. Its configuration is σ1s2σ∗1s2σ2s2σ∗2s2σ2pz2(π2px2=π2py2)(π∗2px1=π∗2py1). Bond order = 210−6=2.0.
- O2+: has 15 electrons (one electron removed from the antibonding π∗ orbital). Bond order = 210−5=2.5.
- O22+: has 14 electrons (two electrons removed from the antibonding π∗ orbitals). Bond order = 210−4=3.0.
- O2−: has 17 electrons (one electron added to the antibonding π∗ orbital). Bond order = 210−7=1.5.
Therefore, the correct decreasing sequence for bond order is O22+(3.0)>O2+(2.5)>O2−(1.5).