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The dissociation equilibrium of a gas AB2AB_2 can be represented as: 2AB2(g)2AB(g)+B2(g)2AB_2(g) \rightleftharpoons 2AB(g) + B_2(g) The degree of dissociation is 'xx' and is small compared to 1. The expression relating the degree of dissociation (xx) with equilibrium constant KpK_p and total pressure pp is:

A

(2Kp/p)(2K_p/p)

B

(2Kp/p)1/3(2K_p/p)^{1/3}

C

(2Kp/p)1/2(2K_p/p)^{1/2}

D

(Kp/p)(K_p/p)

Step-by-Step Solution

Let the initial moles of AB2AB_2 be 1. The dissociation reaction is: 2AB2(g)2AB(g)+B2(g)2AB_2(g) \rightleftharpoons 2AB(g) + B_2(g) Initial moles: 1, 0, 0 Moles at equilibrium: 1x1-x, xx, x/2x/2 Total number of moles at equilibrium = 1x+x+x/2=1+x/21 - x + x + x/2 = 1 + x/2 Partial pressures of the species at equilibrium: pAB2=1x1+x/2×pp_{AB_2} = \frac{1-x}{1+x/2} \times p pAB=x1+x/2×pp_{AB} = \frac{x}{1+x/2} \times p pB2=x/21+x/2×pp_{B_2} = \frac{x/2}{1+x/2} \times p The equilibrium constant KpK_p is given by: Kp=(pAB)2(pB2)(pAB2)2K_p = \frac{(p_{AB})^2 (p_{B_2})}{(p_{AB_2})^2} Kp=(x1+x/2p)2(x/21+x/2p)(1x1+x/2p)2=x3p2(1x)2(1+x/2)K_p = \frac{\left(\frac{x}{1+x/2}p\right)^2 \left(\frac{x/2}{1+x/2}p\right)}{\left(\frac{1-x}{1+x/2}p\right)^2} = \frac{x^3 \cdot p}{2(1-x)^2(1+x/2)} Since xx is small compared to 1, we can approximate 1x11-x \approx 1 and 1+x/211+x/2 \approx 1. Therefore, Kp=x3p2K_p = \frac{x^3 p}{2} x3=2Kppx^3 = \frac{2K_p}{p} x=(2Kpp)1/3x = \left(\frac{2K_p}{p}\right)^{1/3}

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