Let the initial moles of AB2 be 1.
The dissociation reaction is:
2AB2(g)⇌2AB(g)+B2(g)
Initial moles: 1, 0, 0
Moles at equilibrium: 1−x, x, x/2
Total number of moles at equilibrium = 1−x+x+x/2=1+x/2
Partial pressures of the species at equilibrium:
pAB2=1+x/21−x×p
pAB=1+x/2x×p
pB2=1+x/2x/2×p
The equilibrium constant Kp is given by:
Kp=(pAB2)2(pAB)2(pB2)
Kp=(1+x/21−xp)2(1+x/2xp)2(1+x/2x/2p)=2(1−x)2(1+x/2)x3⋅p
Since x is small compared to 1, we can approximate 1−x≈1 and 1+x/2≈1.
Therefore, Kp=2x3p
x3=p2Kp
x=(p2Kp)1/3