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NEET CHEMISTRYMedium

The activation energy for a simple chemical reaction ABA \rightarrow B is EaE_a in a forward direction. The activation energy for the reverse reaction:

A

Is negative of EaE_a

B

Is always less than EaE_a

C

Can be less than or more than EaE_a

D

Is always double of EaE_a

Step-by-Step Solution

The relationship between the activation energy of the forward reaction (Ea(forward)E_{a(forward)}), the activation energy of the backward reaction (Ea(backward)E_{a(backward)}), and the enthalpy of the reaction (ΔH\Delta H) is given by: ΔH=Ea(forward)Ea(backward)\Delta H = E_{a(forward)} - E_{a(backward)}. Rearranging this, we get: Ea(backward)=Ea(forward)ΔHE_{a(backward)} = E_{a(forward)} - \Delta H.

  • If the reaction is exothermic (ΔH\Delta H is negative), then Ea(backward)>Ea(forward)E_{a(backward)} > E_{a(forward)}.
  • If the reaction is endothermic (ΔH\Delta H is positive), then Ea(backward)<Ea(forward)E_{a(backward)} < E_{a(forward)}. Therefore, the activation energy for the reverse reaction can be less than or more than EaE_a depending on whether the reaction is endothermic or exothermic.
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