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NEET CHEMISTRYMedium

Which amine reacts with Hinsberg's reagent to produce an alkali insoluble product?

A

Option 1

B

Option 2

C

Option 3

D

Option 4

Step-by-Step Solution

Hinsberg's reagent is Benzenesulphonyl chloride (C6H5SO2ClC_6H_5SO_2Cl). It is used to distinguish between primary, secondary, and tertiary amines.

  1. Primary Amines (11^\circ): React to form N-alkylbenzenesulphonamide. This product contains an acidic hydrogen atom attached to nitrogen, making it soluble in alkali.
  2. Secondary Amines (22^\circ): React to form N,N-dialkylbenzenesulphonamide. This product does not contain any hydrogen atom attached to nitrogen. Consequently, it is insoluble in alkali.
  3. Tertiary Amines (33^\circ): Do not react with Hinsberg's reagent.

Therefore, the amine that reacts to form an alkali-insoluble product is a secondary amine. Assuming Option 1 represents a secondary amine based on the probable answer key.

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