For the given cell reaction:
Ni(s)+2Ag+(aq)→Ni2+(aq)+2Ag(s)
The number of electrons transferred, n=2.
According to the Nernst equation at 298 K:
Ecell=Ecell∘−n0.059log[Ag+]2[Ni2+]
Substituting the given values:
Ecell∘=1.05 V
[Ni2+]=0.001 M=10−3 M
[Ag+]=0.001 M=10−3 M
Ecell=1.05−20.059log(10−3)210−3
Ecell=1.05−0.0295×log(10−610−3)
Ecell=1.05−0.0295×log(103)
Ecell=1.05−0.0295×3
Ecell=1.05−0.0885
Ecell=0.9615 V