The correct statement among the following is:
the rate of a first-order reaction does not depend on reactant concentration; the rate of a second-order reaction does depend on reactant concentrations.
the half-life of a first-order reaction does not depend on ; the half-life of a second-order reaction does depend on .
a first-order reaction can be catalyzed; a second-order reaction cannot be catalyzed.
the rate of a first-order reaction does depend on reactant concentrations; the rate of a second-order reaction does not depend on reactant concentrations.
For a first-order reaction, the half-life is given by the formula , which clearly shows that it is a constant and is independent of the initial concentration of the reactant . On the other hand, the half-life of a second-order reaction is given by , meaning it is inversely proportional to the initial concentration. The rate of both first-order () and second-order () reactions depends on the reactant concentration. Therefore, only the second statement is correct.
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