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NEET CHEMISTRYMedium

The correct statement among the following is:

A

the rate of a first-order reaction does not depend on reactant concentration; the rate of a second-order reaction does depend on reactant concentrations.

B

the half-life of a first-order reaction does not depend on [A]0[A]_0; the half-life of a second-order reaction does depend on [A]0[A]_0.

C

a first-order reaction can be catalyzed; a second-order reaction cannot be catalyzed.

D

the rate of a first-order reaction does depend on reactant concentrations; the rate of a second-order reaction does not depend on reactant concentrations.

Step-by-Step Solution

For a first-order reaction, the half-life is given by the formula t1/2=0.693kt_{1/2} = \frac{0.693}{k}, which clearly shows that it is a constant and is independent of the initial concentration of the reactant [A]0[A]_0 . On the other hand, the half-life of a second-order reaction is given by t1/2=1k[A]0t_{1/2} = \frac{1}{k[A]_0}, meaning it is inversely proportional to the initial concentration. The rate of both first-order (r=k[A]r = k[A]) and second-order (r=k[A]2r = k[A]^2) reactions depends on the reactant concentration. Therefore, only the second statement is correct.

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