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NEET CHEMISTRYMedium

Iodoform reaction is given by: (a) CH3CH2OHCH_3CH_2OH (b) CH3COCH3CH_3COCH_3 (c) [Compound Missing] (d) CH3OHCH_3OH

A

Only (b)

B

(a), (b) and (c)

C

(a) and (b)

D

(a), (c) and (d)

Step-by-Step Solution

The Iodoform test is positive for compounds containing a methyl ketone group (COCH3-COCH_3) or a methyl carbinol group (CH(OH)CH3-CH(OH)CH_3) attached to at least one hydrogen atom or alkyl/aryl group.

  1. Ethanol (CH3CH2OHCH_3CH_2OH): It contains the CH3CH(OH)CH_3-CH(OH)- group. Upon reaction with iodine and alkali (I2/NaOHI_2/NaOH), it is oxidized to acetaldehyde (CH3CHOCH_3CHO), which contains the CH3C=OCH_3-C=O group, and subsequently yields iodoform (CHI3CHI_3, yellow precipitate).
  2. Acetone (CH3COCH3CH_3COCH_3): It contains the CH3C=OCH_3-C=O group directly. It reacts to form iodoform.
  3. Methanol (CH3OHCH_3OH): It does not contain the requisite methyl group attached to the carbinol carbon. It gives a negative test.

Since both Ethanol (a) and Acetone (b) give the test, the correct selection is '(a) and (b)'.

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