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NEET CHEMISTRYMedium

Aluminium chloride in acidified aqueous solution forms a complex 'A'. The formula of A and hybridisation state of Al in 'A' is respectively:

A

[Al(H₂O)₆]³⁺, sp³d²

B

[Al(H₂O)₄]³⁺, sp³

C

[Al(H₂O)₄]³⁺, dsp²

D

[Al(H₂O)]³⁺, d²sp³

Step-by-Step Solution

Aluminium is a Group 13 element located in the third period. Unlike the first member of the group (Boron), which has a maximum covalency of 4 (e.g., [BF₄]⁻), aluminium has vacant d-orbitals in its valence shell, allowing it to expand its coordination number beyond 4 [Source 70]. In an acidified aqueous solution, aluminium chloride dissolves to form the hexaaquaaluminium(III) ion, where the central metal ion is surrounded by six water molecules. The formula of this complex is [Al(H2O)6]3+[Al(H_2O)_6]^{3+}. To form this octahedral complex, the Al³⁺ ion (electronic configuration [Ne]) utilizes its empty 3s, 3p, and two 3d orbitals for hybridization, resulting in sp³d² hybridisation [Source 30, 70, 111].

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