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Enthalpy change for the reaction, 4H(g)2H2(g)4H(g) \rightarrow 2H_2(g) is 869.6 kJ-869.6 \text{ kJ}. The dissociation energy of the H-H bond is:

A

-869.6 kJ

B
  • 434.8 kJ
C

+217.4 kJ

D

-434.8 kJ

Step-by-Step Solution

The given reaction is the formation of 2 moles of H2H_2 molecules from 4 moles of H atoms: 4H(g)2H2(g);ΔH=869.6 kJ4H(g) \rightarrow 2H_2(g); \Delta H = -869.6 \text{ kJ}

The enthalpy change for the formation of 1 mole of H2H_2 (which involves forming 1 mole of H-H bonds) is: 2H(g)H2(g);ΔH=869.62=434.8 kJ2H(g) \rightarrow H_2(g); \Delta H = \frac{-869.6}{2} = -434.8 \text{ kJ}

The bond dissociation energy is defined as the energy required to break one mole of covalent bonds to form products in the gas phase . This process is the exact reverse of the bond formation reaction: H2(g)2H(g)H_2(g) \rightarrow 2H(g)

Therefore, the enthalpy change for bond dissociation is the positive value of the bond formation enthalpy: ΔbondH=+434.8 kJ\Delta_{bond}H = +434.8 \text{ kJ}.

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