Enthalpy change for the reaction, is . The dissociation energy of the H-H bond is:
-869.6 kJ
+217.4 kJ
-434.8 kJ
The given reaction is the formation of 2 moles of molecules from 4 moles of H atoms:
The enthalpy change for the formation of 1 mole of (which involves forming 1 mole of H-H bonds) is:
The bond dissociation energy is defined as the energy required to break one mole of covalent bonds to form products in the gas phase . This process is the exact reverse of the bond formation reaction:
Therefore, the enthalpy change for bond dissociation is the positive value of the bond formation enthalpy: .
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