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NEET CHEMISTRYEasy

Joule-Thomson expansion is [JIPMER 2000]:

A

Isobaric

B

Isoenthalpic

C

Isothermal

D

None of these

Step-by-Step Solution

Joule-Thomson expansion (also known as the throttling process) involves the expansion of a gas from a high-pressure region to a low-pressure region through a porous plug or restricted valve under adiabatic conditions (q=0q = 0) . According to the first law of thermodynamics, for such a process, the enthalpy (H=U+pVH = U + pV) remains constant from the initial to the final state . Therefore, the process is described as isoenthalpic. While the sources provided discuss Joule's experimental work on internal energy and the definition of enthalpy as a state function, the specific classification of the Joule-Thomson expansion as isoenthalpic is a standard principle in chemical thermodynamics .

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