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NEET CHEMISTRYMedium

The correct order of bond angles in the following compounds/species is:

A

H2O<NH3<NH4+<CO2H_2O < NH_3 < NH_4^+ < CO_2

B

H2O<NH4+<NH3<CO2H_2O < NH_4^+ < NH_3 < CO_2

C

H2O<NH4+=NH3<CO2H_2O < NH_4^+ = NH_3 < CO_2

D

CO2<NH3<H2O<NH4+CO_2 < NH_3 < H_2O < NH_4^+

Step-by-Step Solution

The bond angles of the given species can be determined using VSEPR theory and hybridisation principles described in the sources:

  1. CO2CO_2: The central carbon atom undergoes spsp hybridisation, resulting in a linear geometry with a bond angle of 180180^\circ .
  2. NH4+NH_4^+: The nitrogen atom is sp3sp^3 hybridised and forms four bond pairs with no lone pairs. This results in a regular tetrahedral geometry with a bond angle of 109.5109.5^\circ .
  3. NH3NH_3: The nitrogen atom is sp3sp^3 hybridised but has three bond pairs and one lone pair. According to the sources, lone pair-bond pair (lp-bp) repulsion is greater than bond pair-bond pair (bp-bp) repulsion, which reduces the ideal tetrahedral angle to 107107^\circ .
  4. H2OH_2O: The oxygen atom is sp3sp^3 hybridised with two bond pairs and two lone pairs. Because lone pair-lone pair (lp-lp) repulsion is even stronger than lp-bp repulsion, the bond angle is further reduced to 104.5104.5^\circ .

Comparing these values, the increasing order of bond angles is: H2O(104.5)<NH3(107)<NH4+(109.5)<CO2(180)H_2O (104.5^\circ) < NH_3 (107^\circ) < NH_4^+ (109.5^\circ) < CO_2 (180^\circ).

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