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NEET CHEMISTRYEasy

Half-life period of a first order reaction is 1386 s1386 \text{ s}. The specific rate constant of the reaction is:

A

5.0×103 s15.0 \times 10^{-3} \text{ s}^{-1}

B

0.5×102 s10.5 \times 10^{-2} \text{ s}^{-1}

C

0.5×103 s10.5 \times 10^{-3} \text{ s}^{-1}

D

5.0×102 s15.0 \times 10^{-2} \text{ s}^{-1}

Step-by-Step Solution

For a first-order reaction, the relationship between half-life (t1/2t_{1/2}) and the rate constant (kk) is given by the equation:

t1/2=0.693kt_{1/2} = \frac{0.693}{k}

Rearranging the formula to solve for the rate constant kk:

k=0.693t1/2k = \frac{0.693}{t_{1/2}}

Given the half-life t1/2=1386 st_{1/2} = 1386 \text{ s}, substituting this value into the equation:

k=0.6931386=6931386×1000=12000 s1k = \frac{0.693}{1386} = \frac{693}{1386 \times 1000} = \frac{1}{2000} \text{ s}^{-1}

k=0.0005 s1=5.0×104 s1=0.5×103 s1k = 0.0005 \text{ s}^{-1} = 5.0 \times 10^{-4} \text{ s}^{-1} = 0.5 \times 10^{-3} \text{ s}^{-1}

Therefore, the specific rate constant of the reaction is 0.5×103 s10.5 \times 10^{-3} \text{ s}^{-1}.

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