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NEET CHEMISTRYEasy

An electron-deficient compound among the following is:

A

(SiH₃)₂

B

(BH₃)₂

C

PH₃

D

(CH₃)₂

Step-by-Step Solution

  1. Analyze Octet Fulfillment:
  • (CH₃)₂ (Ethane): Carbon (Group 14) has 4 valence electrons. It forms 4 sigma bonds (3 with H, 1 with C), resulting in a complete octet (8 electrons).
  • (SiH₃)₂ (Disilane): Silicon (Group 14) acts similarly to Carbon, forming 4 bonds and completing its octet.
  • PH₃ (Phosphine): Phosphorus (Group 15) has 5 valence electrons. It forms 3 bonds with H and possesses 1 lone pair. Total valence electrons = 2(lonepair)+6(bonding)=82(lone pair) + 6(bonding) = 8. Octet is complete.
  • (BH₃)₂ (Diborane): Boron (Group 13) has 3 valence electrons. In the monomer BH3BH_3, Boron forms 3 bonds, sharing 6 electrons. This is an incomplete octet (6 < 8), making it electron-deficient. It behaves as a Lewis acid (electron acceptor) [Concept of Lewis acids defined in Class 12 Chemistry, Unit 5, Sec 5.2]. To stabilize, it dimerizes to (BH3)2(BH_3)_2 using 3-center-2-electron bonds.

(Note: Specific details of diborane structure are from standard chemistry curriculum outside the provided text fragments.)

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