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NEET CHEMISTRYMedium

Among the following, the correct order of acidity is:

A

HClO<HClO2<HClO3<HClO4HClO < HClO_2 < HClO_3 < HClO_4

B

HClO2<HClO<HClO3<HClO4HClO_2 < HClO < HClO_3 < HClO_4

C

HClO4<HClO2<HClO<HClO3HClO_4 < HClO_2 < HClO < HClO_3

D

HClO3<HClO4<HClO2<HClOHClO_3 < HClO_4 < HClO_2 < HClO

Step-by-Step Solution

The acidic strength of the oxoacids of a given halogen increases with an increase in the oxidation state of the central halogen atom. The oxidation states of chlorine in HClOHClO, HClO2HClO_2, HClO3HClO_3, and HClO4HClO_4 are +1, +3, +5, and +7, respectively. As the number of highly electronegative oxygen atoms attached to the chlorine atom increases, the electron density of the O-H bond is pulled more strongly towards the Cl-O part of the molecule, weakening the O-H bond and facilitating the easy release of a proton (H+H^+). Additionally, the stability of the corresponding conjugate bases (ClO<ClO2<ClO3<ClO4ClO^- < ClO_2^- < ClO_3^- < ClO_4^-) increases due to the dispersal of the negative charge over more oxygen atoms via resonance. Therefore, the acidity order is HClO<HClO2<HClO3<HClO4HClO < HClO_2 < HClO_3 < HClO_4.

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