Back to Directory
NEET CHEMISTRYMedium

Which of the following ions displays the d-d transition and paramagnetism?

A

CrO42\text{CrO}_4^{2-}

B

Cr2O72\text{Cr}_2\text{O}_7^{2-}

C

MnO4\text{MnO}_4^-

D

MnO42\text{MnO}_4^{2-}

Step-by-Step Solution

To display d-d transition and paramagnetism, the transition metal ion must possess at least one unpaired electron in its d-orbital. Let's calculate the oxidation state and d-electron count for each:

  • In CrO42\text{CrO}_4^{2-} (chromate ion), Cr is in +6+6 oxidation state. Its electronic configuration is 3d03d^0, so it has zero unpaired electrons and is diamagnetic. Its colour is due to ligand-to-metal charge transfer.
  • In Cr2O72\text{Cr}_2\text{O}_7^{2-} (dichromate ion), Cr is also in +6+6 oxidation state (3d03d^0) and is diamagnetic.
  • In MnO4\text{MnO}_4^- (permanganate ion), Mn is in +7+7 oxidation state. Its electronic configuration is 3d03d^0, meaning it is diamagnetic and its colour is due to charge transfer.
  • In MnO42\text{MnO}_4^{2-} (manganate ion), Mn is in +6+6 oxidation state. Its electronic configuration is 3d13d^1. Because it has one unpaired d-electron, it exhibits paramagnetism and displays colour due to d-d transition.
Practice Mode Available

Master this Topic on Sushrut

Join thousands of students and practice with AI-generated mock tests.

Get Started
Solved: CHEMISTRY Question for NEET | Sushrut