To display d-d transition and paramagnetism, the transition metal ion must possess at least one unpaired electron in its d-orbital. Let's calculate the oxidation state and d-electron count for each:
- In CrO42− (chromate ion), Cr is in +6 oxidation state. Its electronic configuration is 3d0, so it has zero unpaired electrons and is diamagnetic. Its colour is due to ligand-to-metal charge transfer.
- In Cr2O72− (dichromate ion), Cr is also in +6 oxidation state (3d0) and is diamagnetic.
- In MnO4− (permanganate ion), Mn is in +7 oxidation state. Its electronic configuration is 3d0, meaning it is diamagnetic and its colour is due to charge transfer.
- In MnO42− (manganate ion), Mn is in +6 oxidation state. Its electronic configuration is 3d1. Because it has one unpaired d-electron, it exhibits paramagnetism and displays colour due to d-d transition.