The manganate and permanganate ions are tetrahedral, due to:
The \pi -bonding involves the overlap of d-orbitals of oxygen with d-orbitals of manganese.
The \pi -bonding involves the overlap of p-orbitals of oxygen with d-orbitals of manganese.
Absence of \pi -bonding.
The \pi -bonding involves the overlap of p-orbitals of oxygen with p-orbitals of manganese.
According to NCERT , both manganate () and permanganate () ions exhibit tetrahedral geometry. The bonding in these oxoanions involves both sigma and \pi character. The -bonding is specifically formed by the lateral overlap of the filled -orbitals of the oxygen atoms with the empty -orbitals of the central manganese atom (known as bonding).
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