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NEET CHEMISTRYMedium

The manganate and permanganate ions are tetrahedral, due to:

A

The \pi -bonding involves the overlap of d-orbitals of oxygen with d-orbitals of manganese.

B

The \pi -bonding involves the overlap of p-orbitals of oxygen with d-orbitals of manganese.

C

Absence of \pi -bonding.

D

The \pi -bonding involves the overlap of p-orbitals of oxygen with p-orbitals of manganese.

Step-by-Step Solution

According to NCERT , both manganate (MnO42MnO_4^{2-}) and permanganate (MnO4MnO_4^-) ions exhibit tetrahedral geometry. The bonding in these oxoanions involves both sigma and \pi character. The π\pi-bonding is specifically formed by the lateral overlap of the filled pp-orbitals of the oxygen atoms with the empty dd-orbitals of the central manganese atom (known as pπdπp\pi-d\pi bonding).

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