To find the final [OH−] concentration, we first need to calculate the milli-moles of H+ and OH− ions.
Milli-moles of H+ from HCl = Molarity × Volume = 0.050 M×20.0 mL=1.0 mmol.
Since each Ba(OH)2 provides two OH− ions, milli-moles of OH− from Ba(OH)2 = 2×Molarity×Volume = 2×0.10 M×30.0 mL=6.0 mmol.
When mixed, H+ will neutralize OH−. The net milli-moles of OH− remaining = 6.0 mmol−1.0 mmol=5.0 mmol.
The total volume of the mixture = 20.0 mL+30.0 mL=50.0 mL.
Therefore, the final concentration of [OH−] = Total VolumeNet milli-moles of OH−=50.0 mL5.0 mmol=0.10 M.