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NEET CHEMISTRYMedium

In which of the following molecules, all atoms are coplanar?

A
B
C

4

D

Step-by-Step Solution

  1. Condition for Coplanarity: A molecule is coplanar if all its constituent atoms lie in the same plane. This usually occurs when the central atoms are sp or sp2^2 hybridised.
  2. Examples from NCERT:
  • Benzene (C6H6C_6H_6): All six carbon atoms are sp2^2 hybridised. The overlapping of sp2sp^2 orbitals forms a hexagonal planar ring structure where all C and H atoms are in the same plane .
  • Ethene (C2H4C_2H_4): Both carbon atoms are sp2^2 hybridised. The molecule is planar with bond angles of approximately 120° .
  • BF3BF_3: The central Boron atom is sp2^2 hybridised, leading to a trigonal planar geometry .
  1. Contrast with Non-planar: Molecules with sp3^3 hybridisation, such as Methane (CH4CH_4) or Ethane (C2H6C_2H_6), possess tetrahedral or puckered geometries and are non-planar .
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