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Which one of the following ions has electronic configuration [Ar]3d6[Ar]3d^6? (At. no: Mn=25,Fe=26,Co=27,Ni=28Mn = 25, Fe = 26, Co = 27, Ni = 28)

A

Ni3+Ni^{3+}

B

Mn3+Mn^{3+}

C

Fe3+Fe^{3+}

D

Co3+Co^{3+}

Step-by-Step Solution

To determine the electronic configuration of ions, electrons are first removed from the outermost shell (4s) and then from the penultimate shell (3d) .

  1. Cobalt (Co): Atomic number Z=27Z=27. Ground state configuration: [Ar]3d74s2[Ar] 3d^7 4s^2. For Co3+Co^{3+}, remove 3 electrons (2 from 4s and 1 from 3d): [Ar]3d6[Ar] 3d^6.

  2. Nickel (Ni): Z=28Z=28. Ground state: [Ar]3d84s2[Ar] 3d^8 4s^2. For Ni3+Ni^{3+}: [Ar]3d7[Ar] 3d^7.

  3. Manganese (Mn): Z=25Z=25. Ground state: [Ar]3d54s2[Ar] 3d^5 4s^2. For Mn3+Mn^{3+}: [Ar]3d4[Ar] 3d^4.

  4. Iron (Fe): Z=26Z=26. Ground state: [Ar]3d64s2[Ar] 3d^6 4s^2. For Fe3+Fe^{3+}: [Ar]3d5[Ar] 3d^5.

Thus, Co3+Co^{3+} corresponds to the [Ar]3d6[Ar] 3d^6 configuration.

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