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NEET CHEMISTRYMedium

Identify the correct relationship of stability from the options provided:

A

TlI>TlI3TlI > TlI_3

B

TlCl3>TlClTlCl_3 > TlCl

C

InI3>InIInI_3 > InI

D

AlCl>AlCl3AlCl > AlCl_3

Step-by-Step Solution

In Group 13 elements, the stability of the higher oxidation state (+3) decreases down the group, while the stability of the lower oxidation state (+1) progressively increases due to the inert pair effect (the reluctance of the valence ns2ns^2 electrons to participate in bonding). For the heaviest element, Thallium (Tl), the +1 oxidation state is much more stable than the +3 oxidation state. Therefore, TlITlI is significantly more stable than TlI3TlI_3. Conversely, for lighter elements like Al, the +3 state is most stable, meaning AlCl3>AlClAlCl_3 > AlCl.

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