Consider the following reaction in a sealed vessel at equilibrium:
2NO(g)⇌N2(g)+O2(g)
[Given: [N2]=3.0×10−3 M, [O2]=4.2×10−3 M and [NO]=2.8×10−3 M]
If 0.1 mol L−1 of NO(g) is taken in a closed vessel, what will be the degree of dissociation (α) of NO(g) at equilibrium?
A
0.0889
B
0.00717
C
0.717
D
0.00889
Step-by-Step Solution
First, calculate the equilibrium constant (Kc) using the given equilibrium concentrations:
2NO(g)⇌N2(g)+O2(g)Kc=[NO]2[N2][O2]Kc=(2.8×10−3)2(3.0×10−3)(4.2×10−3)Kc=7.84×10−612.6×10−6=7.8412.6=1.607
Now, 0.1 mol L−1 of NO is taken in a closed vessel. Let α be its degree of dissociation.
Initial concentration:
[NO]=0.1 M[N2]=0[O2]=0
At equilibrium:
[NO]=0.1−0.1α=0.1(1−α)[N2]=20.1α=0.05α[O2]=20.1α=0.05α
Using the calculated Kc value:
Kc=(0.1(1−α))2(0.05α)(0.05α)1.607=0.01(1−α)20.0025α2=0.25(1−αα)2(1−αα)2=0.251.607=6.428
Taking the square root on both sides:
1−αα=6.428≈2.535α=2.535(1−α)α=2.535−2.535αα+2.535α=2.5353.535α=2.535α=3.5352.535≈0.717
Thus, the degree of dissociation (α) is 0.717.
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