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NEET CHEMISTRYHard

Consider the following reaction in a sealed vessel at equilibrium: 2NO(g)N2(g)+O2(g)2\text{NO}(g) \rightleftharpoons \text{N}_2(g) + \text{O}_2(g) [Given: [N2]=3.0×103 M[\text{N}_2]=3.0 \times 10^{-3}\text{ M}, [O2]=4.2×103 M[\text{O}_2]=4.2 \times 10^{-3}\text{ M} and [NO]=2.8×103 M[\text{NO}]=2.8 \times 10^{-3}\text{ M}] If 0.1 mol L10.1\text{ mol L}^{-1} of NO(g)\text{NO}(g) is taken in a closed vessel, what will be the degree of dissociation (α\alpha) of NO(g)\text{NO}(g) at equilibrium?

A

0.0889

B

0.00717

C

0.717

D

0.00889

Step-by-Step Solution

First, calculate the equilibrium constant (KcK_c) using the given equilibrium concentrations: 2NO(g)N2(g)+O2(g)2\text{NO}(g) \rightleftharpoons \text{N}_2(g) + \text{O}_2(g) Kc=[N2][O2][NO]2K_c = \frac{[\text{N}_2][\text{O}_2]}{[\text{NO}]^2} Kc=(3.0×103)(4.2×103)(2.8×103)2K_c = \frac{(3.0 \times 10^{-3})(4.2 \times 10^{-3})}{(2.8 \times 10^{-3})^2} Kc=12.6×1067.84×106=12.67.84=1.607K_c = \frac{12.6 \times 10^{-6}}{7.84 \times 10^{-6}} = \frac{12.6}{7.84} = 1.607

Now, 0.1 mol L10.1\text{ mol L}^{-1} of NO\text{NO} is taken in a closed vessel. Let α\alpha be its degree of dissociation. Initial concentration: [NO]=0.1 M[\text{NO}] = 0.1\text{ M} [N2]=0[\text{N}_2] = 0 [O2]=0[\text{O}_2] = 0

At equilibrium: [NO]=0.10.1α=0.1(1α)[\text{NO}] = 0.1 - 0.1\alpha = 0.1(1 - \alpha) [N2]=0.1α2=0.05α[\text{N}_2] = \frac{0.1\alpha}{2} = 0.05\alpha [O2]=0.1α2=0.05α[\text{O}_2] = \frac{0.1\alpha}{2} = 0.05\alpha

Using the calculated KcK_c value: Kc=(0.05α)(0.05α)(0.1(1α))2K_c = \frac{(0.05\alpha)(0.05\alpha)}{(0.1(1 - \alpha))^2} 1.607=0.0025α20.01(1α)2=0.25(α1α)21.607 = \frac{0.0025\alpha^2}{0.01(1 - \alpha)^2} = 0.25 \left(\frac{\alpha}{1 - \alpha}\right)^2 (α1α)2=1.6070.25=6.428\left(\frac{\alpha}{1 - \alpha}\right)^2 = \frac{1.607}{0.25} = 6.428 Taking the square root on both sides: α1α=6.4282.535\frac{\alpha}{1 - \alpha} = \sqrt{6.428} \approx 2.535 α=2.535(1α)\alpha = 2.535(1 - \alpha) α=2.5352.535α\alpha = 2.535 - 2.535\alpha α+2.535α=2.535\alpha + 2.535\alpha = 2.535 3.535α=2.5353.535\alpha = 2.535 α=2.5353.5350.717\alpha = \frac{2.535}{3.535} \approx 0.717

Thus, the degree of dissociation (α\alpha) is 0.7170.717.

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