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NEET CHEMISTRYMedium

The chain length of silicones can be controlled by adding:

A

CH3SiCl3CH_3SiCl_3

B

SiCl4SiCl_4

C

(CH3)2SiCl2(CH_3)_2SiCl_2

D

(CH3)3SiCl(CH_3)_3SiCl

Step-by-Step Solution

The chain length of the silicone polymer can be controlled by adding trimethylchlorosilane, (CH3)3SiCl(CH_3)_3SiCl. Upon hydrolysis, it forms trimethylsilanol, (CH3)3SiOH(CH_3)_3SiOH, which contains only one condensable hydroxyl group. It acts as a chain-terminating unit by capping the ends of the polymerizing chain, thus stopping further growth.

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