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NEET CHEMISTRYEasy

What does ZABZ_{AB} represent in the collision theory of chemical reactions?

A

The fraction of molecules with energies greater than EaE_a

B

The collision frequency of reactants, A and B

C

Steric factor

D

The fraction of molecules with energies equal to EaE_a

Step-by-Step Solution

According to the collision theory for a bimolecular elementary reaction A+BProductsA + B \rightarrow \text{Products}, the rate of reaction can be expressed as: Rate=ZABeEa/RT\text{Rate} = Z_{AB}e^{-E_a/RT} In this equation, ZABZ_{AB} represents the collision frequency of reactants A and B, which is defined as the number of collisions per second per unit volume of the reaction mixture. The term eEa/RTe^{-E_a/RT} corresponds to the fraction of molecules with energies equal to or greater than the activation energy (EaE_a). The steric factor (or probability factor), PP, is introduced in modified equations to account for proper orientation, leading to Rate =PZABeEa/RT= PZ_{AB}e^{-E_a/RT} .

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