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NEET CHEMISTRYMedium

The correct statement among the following about [Co(CN)6]3[Co(CN)_6]^{3-} is :

A

It has no unpaired electrons and will be in a low-spin configuration

B

It has four unpaired electrons and will be in a low-spin configuration

C

It has four unpaired electrons and will be in a high-spin configuration

D

It has no unpaired electrons and will be in a high-spin configuration

Step-by-Step Solution

In the complex [Co(CN)6]3[Co(CN)_6]^{3-}, the central metal ion is Cobalt (Co) in the +3 oxidation state. The electronic configuration of Co3+Co^{3+} is 3d63d^6. Since the cyanide ion (CNCN^-) acts as a strong field ligand, the crystal field splitting energy (Δo\Delta_o) is greater than the pairing energy (PP). This leads to the pairing of the six dd-electrons in the lower energy t2gt_{2g} orbitals, resulting in a t2g6eg0t_{2g}^6 e_g^0 configuration. Because all the electrons are paired up, the number of unpaired electrons is zero, making it diamagnetic. It forms an inner-orbital, low-spin complex.

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