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NEET CHEMISTRYEasy

Which of the following compounds will absorb the maximum quantity of heat when dissolved in the same amount of water? The heats of solution (ΔHsol\Delta H_{sol}) of these compounds at 25C25^{\circ}C in kJ/mol of each solute are given in brackets [AMU (Engg.) 2000]:

A

HNO3(ΔH=33)HNO_{3} (\Delta H = -33)

B

KCl(ΔH=+17.64)KCl (\Delta H = +17.64)

C

NH4NO3(ΔH=+25.5)NH_{4}NO_{3} (\Delta H = +25.5)

D

HCl(ΔH=74.1)HCl (\Delta H = -74.1)

Step-by-Step Solution

In thermodynamics, the sign of the enthalpy change (ΔH\Delta H) determines whether a process absorbs or releases energy.

  1. Heat Absorption (Endothermic): Processes that absorb heat from the surroundings have a positive enthalpy change (ΔH>0\Delta H > 0) .
  2. Heat Evolution (Exothermic): Processes that release heat to the surroundings have a negative enthalpy change (ΔH<0\Delta H < 0) .
  3. Enthalpy of Solution (ΔsolH\Delta_{sol}H): This is defined as the enthalpy change when one mole of a substance dissolves in a specified amount of solvent . For most ionic compounds, the dissolution process is endothermic .

Comparing the given heat of solution values:

  • HNO3HNO_{3} (ΔH=33\Delta H = -33): Exothermic; releases heat.
  • KClKCl (ΔH=+17.64\Delta H = +17.64): Endothermic; absorbs heat.
  • NH4NO3NH_{4}NO_{3} (ΔH=+25.5\Delta H = +25.5): Endothermic; absorbs heat.
  • HClHCl (ΔH=74.1\Delta H = -74.1): Exothermic; releases heat.

Since the question asks for the maximum quantity of heat absorbed, we look for the highest positive value. NH4NO3NH_{4}NO_{3} absorbs 25.525.5 kJ of heat per mole, which is greater than the heat absorbed by KClKCl (17.6417.64 kJ/mol). Therefore, Option C is correct.

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