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NEET CHEMISTRYMedium

The stability of +1 oxidation state among Al, Ga, In and Tl increases in the sequence?

A

Ga < In < Al < Tl

B

Al < Ga < In < Tl

C

Tl < In < Ga < Al

D

In < Tl < Ga < Al

Step-by-Step Solution

In Group 13 elements, as we move down the group, the tendency of the ns² valence electrons to remain paired and not participate in bonding increases due to the poor shielding effect of the intervening d and f orbitals. This phenomenon is known as the inert pair effect. Consequently, the stability of the lower oxidation state (+1) increases down the group, while the stability of the higher oxidation state (+3) decreases. Thus, the increasing order of stability of the +1 oxidation state is Al < Ga < In < Tl.

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