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NEET CHEMISTRYMedium

The ionization constant of ammonium hydroxide is 1.77×1051.77 \times 10^{-5} at 298 K298 \text{ K}. Hydrolysis constant of ammonium chloride is:

A

5.65×10105.65 \times 10^{-10}

B

6.50×10126.50 \times 10^{-12}

C

5.65×10135.65 \times 10^{-13}

D

5.65×10125.65 \times 10^{-12}

Step-by-Step Solution

Ammonium chloride (NH4ClNH_4Cl) is a salt of a strong acid (HClHCl) and a weak base (NH4OHNH_4OH). For a salt of a strong acid and a weak base, the hydrolysis constant (KhK_h) is given by the relation: Kh=KwKbK_h = \frac{K_w}{K_b} Where KwK_w is the ionic product of water (101410^{-14} at 298 K298 \text{ K}) and KbK_b is the ionization constant of the weak base. Given: Kb=1.77×105K_b = 1.77 \times 10^{-5} Kw=1.0×1014K_w = 1.0 \times 10^{-14} Substituting the values, we get: Kh=10141.77×105=0.5649×109=5.65×1010K_h = \frac{10^{-14}}{1.77 \times 10^{-5}} = 0.5649 \times 10^{-9} = 5.65 \times 10^{-10}

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