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NEET CHEMISTRYMedium

For a sample of perfect gas when its pressure is changed isothermally from pip_i to pfp_f, the entropy change is given by:

A

ΔS=nRln(pf/pi)\Delta S = nR \ln(p_f/p_i)

B

ΔS=nRln(pi/pf)\Delta S = nR \ln(p_i/p_f)

C

ΔS=nRTln(pf/pi)\Delta S = nRT \ln(p_f/p_i)

D

ΔS=RTln(pf/pi)\Delta S = RT \ln(p_f/p_i)

Step-by-Step Solution

For an ideal (perfect) gas, the change in entropy as a function of temperature and pressure is given by the general equation: ΔS=nCpln(TfTi)+nRln(pipf)\Delta S = nC_p \ln\left(\frac{T_f}{T_i}\right) + nR \ln\left(\frac{p_i}{p_f}\right) For an isothermal process, the temperature remains constant (Ti=TfT_i = T_f), so ln(TfTi)=ln(1)=0\ln\left(\frac{T_f}{T_i}\right) = \ln(1) = 0. Substituting this into the equation, the first term becomes zero, and we are left with: ΔS=nRln(pipf)\Delta S = nR \ln\left(\frac{p_i}{p_f}\right).

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