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NEET CHEMISTRYMedium

More number of oxidation states are exhibited by the actinoids than by the lanthanoids. The main reason for this is:

A

More energy difference between 5f and 6d orbitals than that between 4f and 5d orbitals

B

Lesser energy difference between 5f and 6d orbitals than that between 4f and 5d orbitals

C

Greater metallic character of the lanthanoids than that of the corresponding actinoids

D

More active nature of the actinoids

Step-by-Step Solution

Actinoids exhibit a larger number of oxidation states than lanthanoids because the 5f5f, 6d6d and 7s7s energy levels are of comparable energies (i.e., they have a lesser energy difference). This allows the electrons from all these subshells to participate in bonding and exhibit a wide range of oxidation states. In contrast, the energy difference between 4f4f and 5d5d orbitals in lanthanoids is relatively larger.

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