The correct order of the basic strength of methyl substituted amines in aqueous solution is :
(CH)NH > CHNH > (CH)N
(CH)N > CHNH > (CH)NH
(CH)N > (CH)NH > CHNH
CHNH > (CH)NH > (CH)N
In aqueous solution, electron donating inductive effect, solvation effect (H-bonding) and steric hindrance all together affect basic strength of substituted amines. Basic character: (CH)NH > CHNH > (CH)N.
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