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NEET CHEMISTRYHard

The correct order of the basic strength of methyl substituted amines in aqueous solution is :

1

(CH3_3)2_2NH > CH3_3NH2_2 > (CH3_3)3_3N

2

(CH3_3)3_3N > CH3_3NH2_2 > (CH3_3)2_2NH

3

(CH3_3)3_3N > (CH3_3)2_2NH > CH3_3NH2_2

4

CH3_3NH2_2 > (CH3_3)2_2NH > (CH3_3)3_3N

Step-by-Step Solution

In aqueous solution, electron donating inductive effect, solvation effect (H-bonding) and steric hindrance all together affect basic strength of substituted amines. Basic character: (CH3_3)2_2NH > CH3_3NH2_2 > (CH3_3)3_3N.

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