A magnetic moment of 1.73 BM will be shown by one among the following:
A
[Cu(NH3)4]2+
B
[Ni(CN)4]2−
C
TiCl4
D
[CoCl6]4−
Step-by-Step Solution
The spin-only magnetic moment (μ) is given by the formula μ=n(n+2) BM, where n is the number of unpaired electrons. For a magnetic moment of 1.73 BM, the number of unpaired electrons must be n=1 (since 1(1+2)=3≈1.73).
[Cu(NH3)4]2+: The central metal ion is Cu in the +2 oxidation state. The electronic configuration of Cu2+ is [Ar]3d9. It has 1 unpaired electron (n=1). Thus, its spin-only magnetic moment μ=1.73 BM .
[Ni(CN)4]2−: The central metal ion is Ni in the +2 oxidation state ([Ar]3d8). The cyanide ion (CN−) is a strong field ligand, which causes the pairing of the two unpaired d electrons. It has 0 unpaired electrons (n=0), making it diamagnetic. Thus, μ=0 BM .
TiCl4: The central metal ion is Ti in the +4 oxidation state ([Ar]3d0). It has no d electrons and hence 0 unpaired electrons (n=0). Thus, μ=0 BM.
[CoCl6]4−: The central metal ion is Co in the +2 oxidation state ([Ar]3d7). The chloride ion (Cl−) is a weak field ligand, so no pairing of electrons takes place. It has 3 unpaired electrons (n=3). Thus, μ=3(3+2)=15≈3.87 BM .
Therefore, [Cu(NH3)4]2+ is the complex that shows a magnetic moment of 1.73 BM.
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