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NEET CHEMISTRYEasy

The rate constant for a first order reaction is 4.606 × 10⁻³ s⁻¹. The time required to reduce 2.0 g of the reactant to 0.2 g is:

A

200 s

B

500 s

C

1000 s

D

100 s

Step-by-Step Solution

For a first-order reaction, the integrated rate equation is given by: t=2.303klog[R]0[R]t = \frac{2.303}{k} \log \frac{[R]_0}{[R]} where: tt is the time required, kk is the rate constant = 4.606×103 s14.606 \times 10^{-3} \text{ s}^{-1}, [R]0[R]_0 is the initial concentration (or mass) = 2.0 g, [R][R] is the final concentration (or mass) = 0.2 g.

Substituting the values into the equation: t=2.3034.606×103log(2.00.2)t = \frac{2.303}{4.606 \times 10^{-3}} \log \left( \frac{2.0}{0.2} \right) t=12×103log(10)t = \frac{1}{2 \times 10^{-3}} \log(10) Since log(10)=1\log(10) = 1: t=10002=500 st = \frac{1000}{2} = 500 \text{ s} .

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