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NEET CHEMISTRYMedium

If the bond energies of HH\text{H}-\text{H}, BrBr\text{Br}-\text{Br}, and HBr\text{H}-\text{Br} are 433433, 192192, and 364 kJ mol1364\text{ kJ mol}^{-1} respectively, the ΔH\Delta H^\circ for the reaction H2(g)+Br2(g)2HBr(g)\text{H}_2(g) + \text{Br}_2(g) \rightarrow 2\text{HBr}(g) will be:

A

+103 kJ+103\text{ kJ}

B

+261 kJ+261\text{ kJ}

C

103 kJ-103\text{ kJ}

D

261 kJ-261\text{ kJ}

Step-by-Step Solution

The standard enthalpy of reaction (ΔrH\Delta_r H^\circ) can be calculated from the bond energies of the reactants and products using the formula: ΔrH=Bond energies of reactantsBond energies of products\Delta_r H^\circ = \sum \text{Bond energies of reactants} - \sum \text{Bond energies of products} For the reaction: H2(g)+Br2(g)2HBr(g)\text{H}_2(g) + \text{Br}_2(g) \rightarrow 2\text{HBr}(g) ΔrH=[BE(HH)+BE(BrBr)][2×BE(HBr)]\Delta_r H^\circ = [\text{BE}(\text{H}-\text{H}) + \text{BE}(\text{Br}-\text{Br})] - [2 \times \text{BE}(\text{H}-\text{Br})] Given values: BE(HH)=433 kJ mol1\text{BE}(\text{H}-\text{H}) = 433\text{ kJ mol}^{-1} BE(BrBr)=192 kJ mol1\text{BE}(\text{Br}-\text{Br}) = 192\text{ kJ mol}^{-1} BE(HBr)=364 kJ mol1\text{BE}(\text{H}-\text{Br}) = 364\text{ kJ mol}^{-1} Substituting the values: ΔrH=[433+192][2×364]\Delta_r H^\circ = [433 + 192] - [2 \times 364] ΔrH=625728\Delta_r H^\circ = 625 - 728 ΔrH=103 kJ\Delta_r H^\circ = -103\text{ kJ}

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