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NEET CHEMISTRYMedium

The work done when 1 mole1 \text{ mole} of gas expands reversibly and isothermally from a pressure of 5 atm5 \text{ atm} to 1 atm1 \text{ atm} at 300 K300 \text{ K} is: [Given: log5=0.6989\log 5 = 0.6989 and R=8.314 J K1 mol1R = 8.314 \text{ J K}^{-1} \text{ mol}^{-1}]

A

Zero J

B

150 J

C

+4014.6 J

D

-4014.6 J

Step-by-Step Solution

For an isothermal reversible expansion of an ideal gas, the work done (ww) is given by the formula: w=2.303nRTlog(pipf)w = -2.303 nRT \log\left(\frac{p_i}{p_f}\right) Given data: Number of moles, n=1 molen = 1 \text{ mole} Temperature, T=300 KT = 300 \text{ K} Initial pressure, pi=5 atmp_i = 5 \text{ atm} Final pressure, pf=1 atmp_f = 1 \text{ atm} Gas constant, R=8.314 J K1mol1R = 8.314 \text{ J K}^{-1} \text{mol}^{-1} log5=0.6989\log 5 = 0.6989 Substituting the values into the formula: w=2.303×1×8.314×300×log(51)w = -2.303 \times 1 \times 8.314 \times 300 \times \log\left(\frac{5}{1}\right) w=2.303×2494.2×log5w = -2.303 \times 2494.2 \times \log 5 w=5744.14×0.69894014.6 Jw = -5744.14 \times 0.6989 \approx -4014.6 \text{ J} The negative sign indicates that work is done by the system (expansion) .

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