Activation energy of any chemical reaction can be calculated if one knows the value of:
Probability of collision.
Orientation of reactant molecules during collision.
Rate constant at two different temperatures.
Rate constant at standard temperature.
According to the Arrhenius equation, the relationship between the rate constant and temperature is given by: where and are the rate constants at temperatures and respectively, is the activation energy, and is the gas constant. Thus, if the rate constants at two different temperatures are known, the activation energy of the reaction can be easily calculated.
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