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NEET CHEMISTRYMedium

The energy of electron in the ground state (n=1n=1) for He+He^+ ion is x-x J, then that for an electron in n=2n=2 state for Be3+Be^{3+} ion in J is:

A

x9-\frac{x}{9}

B

4x-4x

C

49x-\frac{4}{9}x

D

x-x

Step-by-Step Solution

According to Bohr's theory for hydrogen-like species, the energy of an electron in the nn-th orbit is given by the expression: En=E0×Z2n2E_n = E_0 \times \frac{Z^2}{n^2} where E0E_0 is the ground state energy of hydrogen (2.18×1018-2.18 \times 10^{-18} J) and ZZ is the atomic number.

  1. For Helium ion (He+He^+): Atomic number Z=2Z = 2. Ground state n=1n = 1.
  • Given Energy E=xE = -x J. EHe+2212=4E_{He^+} \propto \frac{2^2}{1^2} = 4 So, x4-x \propto 4.
  1. For Beryllium ion (Be3+Be^{3+}): Atomic number Z=4Z = 4. Excited state n=2n = 2. EBe3+4222=164=4E_{Be^{3+}} \propto \frac{4^2}{2^2} = \frac{16}{4} = 4

  2. Comparison: Since the value proportional to the energy depends on Z2n2\frac{Z^2}{n^2}, and for both cases this ratio is 4, the energies are equal. EBe3+=EHe+=x JE_{Be^{3+}} = E_{He^+} = -x \text{ J}

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