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NEET CHEMISTRYEasy

BF3BF_3 is a planar and an electron-deficient compound. Hybridisation and the number of electrons around the central atom, respectively, are:

A

sp2sp^2 and 6

B

sp2sp^2 and 8

C

sp3sp^3 and 4

D

sp3sp^3 and 6

Step-by-Step Solution

According to the principles of chemical bonding and molecular structure:

  1. Electronic Configuration: Boron (BB, atomic number 5) has the electronic configuration 1s22s22p11s^2 2s^2 2p^1 . In its excited state, one electron from the 2s2s orbital is promoted to a 2p2p orbital, providing three unpaired electrons .
  2. Hybridisation: These three orbitals (one ss and two pp) intermix to form three equivalent sp2sp^2 hybrid orbitals .
  3. Geometry: These sp2sp^2 hybrid orbitals are oriented in a trigonal planar arrangement with bond angles of 120120^\circ .
  4. Electron Count: Boron forms three sigma bonds with three fluorine atoms. Each bond consists of a shared pair of electrons, resulting in a total of 6 valence electrons around the central boron atom .
  5. Electron Deficiency: Since the boron atom has only 6 electrons in its valence shell, it does not complete its octet, which explains why BF3BF_3 is an electron-deficient compound and acts as a Lewis acid .

Therefore, the hybridisation is sp2sp^2 and the number of electrons around the central atom is 6.

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