Mechanism of a hypothetical reaction is given below: (i) (fast) (ii) (slow) (iii) (fast) The overall order of the reaction will be:
1
2
0
1.5
The overall rate of a complex reaction is governed by the slowest step, which is the rate-determining step (RDS). From the given mechanism, the slowest step is: Therefore, the rate law based on the slowest step is: Since is an intermediate formed in a fast equilibrium step, its concentration must be expressed in terms of the reactants using the equilibrium step: The equilibrium constant is: Substituting back into the rate equation gives: (where ) The overall order of the reaction is the sum of the powers of the concentration terms in the rate law:
Join thousands of students and practice with AI-generated mock tests.