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Mechanism of a hypothetical reaction X2+Y22XYX_2 + Y_2 \rightarrow 2XY is given below: (i) X2X+XX_2 \rightleftharpoons X + X (fast) (ii) X+Y2XY+YX + Y_2 \rightarrow XY + Y (slow) (iii) X+YXYX + Y \rightarrow XY (fast) The overall order of the reaction will be:

A

1

B

2

C

0

D

1.5

Step-by-Step Solution

The overall rate of a complex reaction is governed by the slowest step, which is the rate-determining step (RDS). From the given mechanism, the slowest step is: X+Y2XY+YX + Y_2 \rightarrow XY + Y Therefore, the rate law based on the slowest step is: Rate=k[X][Y2]\text{Rate} = k[X][Y_2] Since XX is an intermediate formed in a fast equilibrium step, its concentration must be expressed in terms of the reactants using the equilibrium step: X22XX_2 \rightleftharpoons 2X The equilibrium constant KcK_c is: Kc=[X]2[X2]K_c = \frac{[X]^2}{[X_2]} [X]2=Kc[X2]\Rightarrow [X]^2 = K_c[X_2] [X]=Kc1/2[X2]1/2\Rightarrow [X] = K_c^{1/2}[X_2]^{1/2} Substituting [X][X] back into the rate equation gives: Rate=k(Kc1/2[X2]1/2)[Y2]\text{Rate} = k \cdot (K_c^{1/2}[X_2]^{1/2}) \cdot [Y_2] Rate=k[X2]1/2[Y2]1\text{Rate} = k' [X_2]^{1/2}[Y_2]^1 (where k=kKc1/2k' = k \cdot K_c^{1/2}) The overall order of the reaction is the sum of the powers of the concentration terms in the rate law: Overall order=12+1=1.5\text{Overall order} = \frac{1}{2} + 1 = 1.5

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