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NEET CHEMISTRYMedium

The number of unpaired electrons in a paramagnetic diatomic molecule of an element with atomic mass 1616 is:

A

2

B

3

C

4

D

1

Step-by-Step Solution

The element with an atomic mass of 1616 is oxygen (O). Its diatomic molecule is O2\text{O}_2, which contains a total of 1616 electrons. According to the Molecular Orbital Theory, the electronic configuration of the O2\text{O}_2 molecule is: σ1s2,σ1s2,σ2s2,σ2s2,σ2pz2,(π2px2=π2py2),(π2px1=π2py1)\sigma 1s^2, \sigma^* 1s^2, \sigma 2s^2, \sigma^* 2s^2, \sigma 2p_z^2, (\pi 2p_x^2 = \pi 2p_y^2), (\pi^* 2p_x^1 = \pi^* 2p_y^1) As seen from the configuration, there are 22 unpaired electrons present in the degenerate π2px\pi^* 2p_x and π2py\pi^* 2p_y antibonding molecular orbitals. This presence of unpaired electrons is responsible for the paramagnetic nature of the oxygen molecule.

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