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NEET CHEMISTRYHard

The value of Kp1K_{p_1} and Kp2K_{p_2} for the reactions XY+ZX \rightleftharpoons Y + Z ...(i) and A2BA \rightleftharpoons 2B ...(ii) are in the ratio of 9:19 : 1. If the degree of dissociation of X and A is equal, then the total pressure at equilibrium (i) and (ii) are in the ratio:

A

3 : 1

B

1 : 9

C

36 : 1

D

1 : 1

Step-by-Step Solution

For the reaction XY+ZX \rightleftharpoons Y + Z: Initial moles: 1, 0, 0 Moles at equilibrium: 1α1-\alpha, α\alpha, α\alpha Total moles at equilibrium = 1α+α+α=1+α1 - \alpha + \alpha + \alpha = 1 + \alpha Partial pressures: pX=1α1+αP1p_X = \frac{1-\alpha}{1+\alpha} P_1, pY=α1+αP1p_Y = \frac{\alpha}{1+\alpha} P_1, pZ=α1+αP1p_Z = \frac{\alpha}{1+\alpha} P_1 Kp1=pYpZpX=(α1+αP1)(α1+αP1)1α1+αP1=α21α2P1K_{p_1} = \frac{p_Y p_Z}{p_X} = \frac{(\frac{\alpha}{1+\alpha} P_1)(\frac{\alpha}{1+\alpha} P_1)}{\frac{1-\alpha}{1+\alpha} P_1} = \frac{\alpha^2}{1-\alpha^2} P_1

For the reaction A2BA \rightleftharpoons 2B: Initial moles: 1, 0 Moles at equilibrium: 1α1-\alpha, 2α2\alpha Total moles at equilibrium = 1α+2α=1+α1 - \alpha + 2\alpha = 1 + \alpha Partial pressures: pA=1α1+αP2p_A = \frac{1-\alpha}{1+\alpha} P_2, pB=2α1+αP2p_B = \frac{2\alpha}{1+\alpha} P_2 Kp2=pB2pA=(2α1+αP2)21α1+αP2=4α21α2P2K_{p_2} = \frac{p_B^2}{p_A} = \frac{(\frac{2\alpha}{1+\alpha} P_2)^2}{\frac{1-\alpha}{1+\alpha} P_2} = \frac{4\alpha^2}{1-\alpha^2} P_2

Given Kp1Kp2=91\frac{K_{p_1}}{K_{p_2}} = \frac{9}{1} α21α2P14α21α2P2=P14P2=91\frac{\frac{\alpha^2}{1-\alpha^2} P_1}{\frac{4\alpha^2}{1-\alpha^2} P_2} = \frac{P_1}{4P_2} = \frac{9}{1} P1P2=361\frac{P_1}{P_2} = \frac{36}{1} Therefore, the ratio of total pressures at equilibrium is 36:136 : 1.

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