For the reaction X⇌Y+Z:
Initial moles: 1, 0, 0
Moles at equilibrium: 1−α, α, α
Total moles at equilibrium = 1−α+α+α=1+α
Partial pressures: pX=1+α1−αP1, pY=1+ααP1, pZ=1+ααP1
Kp1=pXpYpZ=1+α1−αP1(1+ααP1)(1+ααP1)=1−α2α2P1
For the reaction A⇌2B:
Initial moles: 1, 0
Moles at equilibrium: 1−α, 2α
Total moles at equilibrium = 1−α+2α=1+α
Partial pressures: pA=1+α1−αP2, pB=1+α2αP2
Kp2=pApB2=1+α1−αP2(1+α2αP2)2=1−α24α2P2
Given Kp2Kp1=19
1−α24α2P21−α2α2P1=4P2P1=19
P2P1=136
Therefore, the ratio of total pressures at equilibrium is 36:1.